Search results for " crack"

High-temperature in-process inspection followed by 96-h robotic inspection of intentionally manufactured hydrogen crack in multi-pass robotic welding

2021

Abstract This investigation introduces two new techniques to quantitatively address the challenging problem of understanding Hydrogen Induced Cracking (HIC) in welding processes. The first technique is a novel procedure to create a known and controlled HIC in a welded sample. The second is an in-process monitoring technique to measure the initial formation and subsequent growth of the HIC in a multi-pass weld whilst being compatible with the high temperatures associated with the welding process. The HIC was initiated using a localised quenching method of the weld and its character was verified using both macrograph and microscopic investigations. During HIC initiation and growth, the sample…

A Novel Biomimetic Approach to Repair Enamel Cracks/Carious Damages and to Reseal Dentinal Tubules by Amorphous Polyphosphate.

2017

Based on natural principles, we developed a novel toothpaste, containing morphogenetically active amorphous calcium polyphosphate (polyP) microparticles which are enriched with retinyl acetate (“a-polyP/RA-MP”). The spherical microparticles (average size, 550 ± 120 nm), prepared by co-precipitating soluble Na-polyP with calcium chloride and supplemented with retinyl acetate, were incorporated into a base toothpaste at a final concentration of 1% or 10%. The “a-polyP/RA-MP” ingredient significantly enhanced the stimulatory effect of the toothpaste on the growth of human mesenchymal stem cells (MSC). This increase was paralleled by an upregulation of the MSC marker genes for osteoblast differ…

Vertical Root Fracture initiation in curved roots after root canal preparation : a dentinal micro-crack analysis with LED transillumination

2017

Background One of the causative factors of root defects is the increased friction produced by rotary instrumentation. A high canal curvature may increase stress, making the tooth more susceptible to dentinal cracks. The purpose of this study was to evaluate dentinal micro-crack formation with the ProTaper NEXT and ProTaper Universal systems using LED transillumination, and to analyze the micro-crack generated at the point of maximum canal curvature. Material and Methods 60 human mandibular premolars with curvatures between 30–49° and radii between 2–4 mm were used. The root canals were instrumented using the Protaper Universal® and Protaper NEXT® systems, with the aid of the Proglider® syst…

Reclaimed asphalt binders and mortars fatigue behaviour

2017

Fatigue cracking is one of the most important failure mechanisms occurring in asphalt pavements, especially when mixtures incorporate considerable amount of rReclaimed asphalt pavement (RAP). In fact, aged binders contained in RAP generally make asphalt more brittle and specifically reduce fatigue resistance of the resulting asphalt mixtures. Binders and mortars play a key role in this phenomenon, considering fatigue cracking usually starts within these asphalt components. However, performance-related tests and specifications commonly regard binders and there are no sound methodologies allowing the use of mortars to predicting fatigue performance of asphalts containing RAP. For this reason,…

Automatic crack detection results using a novel device for survey and analysis of road pavement condition

2019

To accurately schedule maintenance operations, it is crucial to monitor the pavement state and, thus, evaluate the structural and functional indices during its entire service life. In particular, surface conditions (cracks, potholes, patches, rutting, etc.) must be properly checked – especially in terms of detection, identification, and classification of distresses – for avoiding reaching dangerous values for users (overpassing safety thresholds). However, monitoring and survey activities can be so costly (not only in economic terms, but further considering the execution time) to discourage their execution, with evident drawbacks for a proper maintenance management and the related intervent…

Can Macroscopic Parameters, Such as Conversion and Selectivity, Distinguish between Different Cracking Mechanisms on Acid Catalysts?

1997

n-heptane cracking has been carried out for very short time periods on an established reaction mechanism which includes the following group of stream reactions on different zeolites: Initiation reactions (protolytic cracking), charge isomerization, chain isomerization, hydride transfer, β-scission–alkylation, desorption–adsorption, and hydrogen transfer–cyclization. It has been observed that a given experimental distribution of products can be explained by more than just one reaction scheme. This does not allow one to clearly distinguish the fraction of reactant which disappears via monomolecular initiation reactions with respect to bimolecular hydride transfer reactions.

BE contact analysis of delamination cracks actively repaired trhough piezoelectric active patches

2009

Selective Introduction of Acid Sites in Different Confined Positions in ZSM-5 and Its Catalytic Implications

2018

Controlling the location of acid sites in zeolites can have a great effect on catalysis. In this work we face the objective of directing the location of Al into the 10R channels of ZSM-5 by taking advantage of the structural preference of B to occupy certain positions at the channel intersections, as suggested by theoretical calculations. The synthesis of B-Al-ZSM-5 zeolites with variable Si/Al and Si/B ratios, followed by B removal in a postsynthesis treatment, produces ZSM-5 samples enriched in Al occupying positions at 10R channels. The location of the acid sites is determined on the basis of the product distribution of 1-hexene cracking as a test reaction. The higher selectivity to prop…

Catalytic cracking of alkanes on MCM-22 zeolite. Comparison with ZSM-5 and beta zeolite and its possibility as an FCC cracking additive

1995

Abstract N-heptane cracking has been carried out on MCM-22, and its kinetic and decay behaviour is compared with that of ZSM-5 and Beta zeolites. In the case of MCM-22 cracking occurs in the 10-member ring channel system, as well as in the large cavities formed by 12-member rings. Product selectivities show that MCM-22, while presenting features which indicate structural similarities with ZSM-5, it also presents characteristics corresponding to pores or cavities larger than ZSM-5. The selectivities to the individual products together with C1 + C2/iC4, C3/C4, C5/C2, iC4/total C4, and alkane/alkene ratios indicate that MCM-22 has good properties to be used as an FCC octane booster additive sp…

Formation of products responsible for motor and research octane of gasolines produced by cracking The implication of framework Si/Al ratio and operat…

1989

Abstract An alkane in the range of gasoline fraction ( n -heptane) has been used as a reactant to study the influence of zeolite Y catalyst and process variables (i.e., framework Si Al ratio and procedure of dealumination, time on stream, and contact time) on the formation of products responsible for motor and research octane of gasoline during cracking, namely branched, aromatics, and olefins. It is found that the branched isomers in the C 5 and C 6 fractions appear as primary products and are partly produced by disproportionation, since the ratio of iso to normal compounds is above equilibrium. The ratio of branched to linear products strongly decreases when the number of carbon atoms of …